Name | Neodymium carbonate |
Synonyms | Neodymium carbonate NEODYMIUM (III) CARBONATE Neodymium carbonate hydrate NEODYMIUM CARBONATE HYDRATE NEODYMIUM CARBONATE, HYDROUS NEODYMIUM CARBONATE OCTAHYDRATE Neodymium(III) carbonate hydrate NEODYMIUM(III) CARBONATE HYDRATE |
CAS | 38245-38-4 |
EINECS | 628-324-3 |
InChI | InChI=1/3CH2O3.2Nd.H2O/c3*2-1(3)4;;;/h3*(H2,2,3,4);;;1H2/q;;;2*+3;/p-6 |
Molecular Formula | 3CO3.2Nd |
Molar Mass | 468.5 |
Melting Point | 114°C(lit.) |
Boling Point | 333.6°C at 760 mmHg |
Flash Point | 169.8°C |
Water Solubility | Insoluble in water, moderately soluble in strong mineral acids. |
Vapor Presure | 2.58E-05mmHg at 25°C |
Appearance | Powder |
Color | light purple |
Storage Condition | Room Temprature |
MDL | MFCD00150426 |
Physical and Chemical Properties | Light pink or light purple crystalline powder, orthorhombic crystal system. Soluble in acid, insoluble in water. When the aqueous suspension is boiled, the basic carbonate is produced by hydrolysis. The formation of insoluble carbonate salt Nd2(CO3)3 in alkali metal carbonate solution? NaCO3? H2O. Can react with most acids to form the corresponding salt. This was converted to neodymium oxide by ignition to 800 °c. |
Use | Used for glass decolorizing agent, colorant and capacitor material |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
WGK Germany | 2 |
RTECS | FG1960000 |
TSCA | Yes |
light pink or light purple crystalline powder, belonging to orthorhombic system. Soluble in acid, insoluble in water. When the aqueous suspension is boiled, the basic carbonate is produced by hydrolysis. In the alkali metal carbonate solution to produce insoluble carbonate salt Nd2(C03)3. Nac3/h20. Can react with most acids to form the corresponding salt. This was converted to neodymium oxide by ignition to 800 °c.
solvent extraction method: the raw material is the rare earth back extraction solution after extracting lanthanum with dimethyl heptyl methylphosphonate (P350), which is concentrated to contain total Re. Rare earth solution of Oy 150g/L, HNO 30. 3mol/L. The first step with di (2-ethylhexyl) phosphoric acid (P204)-kerosene solution of neodymium samarium grouping, the second step with trialkylmethylamine chloride (N263)-kerosene solution extraction neodymium, an acidic solution of neodymium nitrate was obtained. The product is neutralized with ammonia, added ammonium bicarbonate to precipitate neodymium carbonate at a lower temperature, filtered, washed, centrifuged and dried.
used as a decolorizing agent and a coloring agent for glass.
toxicity and protection see cerium oxide products.
application | neodymium carbonate can be used to make ternary catalysts, magnetic materials, neodymium compound intermediates, chemical reagents, etc. |
Preparation | Neodymium carbonate can be obtained from the hydrolysis of neodymium trichloroacetate: 2 Nd(C2Cl3O2)3 3 H2O → Nd2(CO3)3 6 CHCl3 3 CO2 Another method is to react neodymium chloride and ammonium bicarbonate in water. |
toxicity | see cerium oxide products. |
use | used as decolorant and colorant for glass. used for glass decolorant, colorant and capacitor materials, etc. scientific research reagents, biochemical research |
production method | solvent extraction method raw material is rare earth stripping solution after lanthanum extraction from dimethyl heptyl methylphosphonate (P350), concentrated into total RexOy150/L,. FINO30.3 mol/L rare earth solution. The first step uses bis (2-ethylhexyl) phosphoric acid (P2O4)-kerosene solution to group neodymium samarium, and the second step uses trialkylmethylamine chloride (N263)-kerosene solution to extract neodymium to obtain acid Neodymium nitrate solution. Neutralize with ammonia water, add ammonium bicarbonate at a lower temperature to precipitate neodymium carbonate, filter, wash, centrifuge, and dry the product. |